here's another type of question you can 这是您可以提出的另一种问题
here's another type of question you can 得到高度的重视
here's another type of question you can get regard as you will in height 他们相距两个单位是108
get regard as you will in height 110对，这是一个分子离子，
get regard as you will in height they are two units apart it's 108 and M加两个几乎相等的峰
they are two units apart it's 108 and 卤素的高度
they are two units apart it's 108 and 110 right so that's a molecular ion and 对应于溴，就是这样
110 right so that's a molecular ion and 只要您记得
110 right so that's a molecular ion and an M plus two peak that are almost equal 只要记住同位素比
an M plus two peak that are almost equal 知道那是溴
an M plus two peak that are almost equal height in which halogen does that 考虑一点
height in which halogen does that 碎片模式，因此您可以
height in which halogen does that correspond to bromine right it's that 分子离子可能是溴作为原子
correspond to bromine right it's that 掉下来，所以激进与
correspond to bromine right it's that easy as long as you remember that as 留下溴和烷基
easy as long as you remember that as 阳离子，所以一旦溴脱落
easy as long as you remember that as long as you remember the isotope ratios 你输了80，你就输了
long as you remember the isotope ratios 到这里好吧那是
long as you remember the isotope ratios and knowing that that's bromine and 实际上从108个峰值中损失了79个
and knowing that that's bromine and 实际上是从110损失81
and knowing that that's bromine and thinking a little bit about 高峰都导致29 29是
thinking a little bit about 大量的阳离子阳离子好吗
thinking a little bit about fragmentation patterns so you make a 伙计们没事了
fragmentation patterns so you make a 用质谱手段深入研究
fragmentation patterns so you make a molecular ion maybe bromine as an atom 看碎片模式，
molecular ion maybe bromine as an atom 问自己可能会发生什么
molecular ion maybe bromine as an atom falls off so the radical goes with the 好，所以有两个共同点
falls off so the radical goes with the 发生的碎片化模式
falls off so the radical goes with the bromine leaves behind and an alkyl 实际上，您只需要两个
bromine leaves behind and an alkyl 关心两种方式
bromine leaves behind and an alkyl cation and so once the bromine falls off 分解我已经给你看过一个
cation and so once the bromine falls off 自由基阳离子分裂成一个
cation and so once the bromine falls off you're losing 80 and you're going down 一部分是激进的，另一部分是
you're losing 80 and you're going down 拿阳离子
you're losing 80 and you're going down to here oh well how about that so it's 我们没有看过的第二只宠物是
to here oh well how about that so it's 该分子释放出什么中性分子
to here oh well how about that so it's actually losing 79 from the 108 peak and 分子，所以中性分子吐出
actually losing 79 from the 108 peak and 现在如果自由基阳离子分子
actually losing 79 from the 108 peak and it's actually losing 81 from the 110 碎片艺术比
it's actually losing 81 from the 110 中性模型丢失意味着
it's actually losing 81 from the 110 peak both of those lead to 29 29 is the 中性钼既不偏激也不偏激
peak both of those lead to 29 29 is the 与它的阳离子
peak both of those lead to 29 29 is the mass of ethyl as a cation okay did you 因此，两者都留在了
mass of ethyl as a cation okay did you 其他片段，所以它说在这里
mass of ethyl as a cation okay did you guys catch that all right 所以你得到了自由基阳离子为什么ROH是
guys catch that all right 在括号中是因为这是
guys catch that all right digging deeper with mass spec means 酒精非常常见
digging deeper with mass spec means 容易失去水有他们的中立
digging deeper with mass spec means looking at the fragmentation pattern and 分子，然后是新的自由基阳离子
looking at the fragmentation pattern and 经常会进一步破碎以给予
looking at the fragmentation pattern and asking yourself what's likely going on 其他山峰，再次记得那里有一个
asking yourself what's likely going on 质谱中发生的很多事情
asking yourself what's likely going on okay so there are two common 需要解释是
okay so there are two common 解决问题就像
okay so there are two common fragmentation patterns that happen 用红外好吧，这就是其他
fragmentation patterns that happen 酒精的破碎途径
fragmentation patterns that happen actually there only two that you need to 将会流失水分
actually there only two that you need to 水说这成了问题
actually there only two that you need to be concerned about two ways you can 现在这是常规化学，尽管所有
be concerned about two ways you can 对
be concerned about two ways you can break down I already showed you the one 这里没有什么特别的
break down I already showed you the one 所以你最初的电离事件是
break down I already showed you the one the radical cation fragments into one 这里发生了什么，电子是
the radical cation fragments into one 我想我现在失去了忠告
the radical cation fragments into one part being the radical the other part be 不知道您何时考虑
part being the radical the other part be 更复杂分子中的电子
part being the radical the other part be taking the cation 或可能会丢失 68 电子比电子容易丢失
the second pet we haven't looked at is 其他人，这一切都取决于你知道
the second pet we haven't looked at is 考虑一下能量图
the second pet we haven't looked at is that molecule what to liberate a neutral 我们看过谁知道多少次
that molecule what to liberate a neutral 上学期电子坐在能量中
that molecule what to liberate a neutral molecule so a neutral molecule spits out 正确的水平，通常是那些
molecule so a neutral molecule spits out 最容易失去的是那些
molecule so a neutral molecule spits out now if the radical cation the molecular 最高，因为他们有他们
now if the radical cation the molecular 有更少的距离旅行成为
now if the radical cation the molecular art for fragments in such a way than a 自由电子等
art for fragments in such a way than a 酒类
art for fragments in such a way than a neutral model is lost that means the 最容易的电子是什么
neutral model is lost that means the 失去的是孤独的
neutral model is lost that means the neutral moly take a neither radical nor 对他们去的氧气他们去
neutral moly take a neither radical nor 很容易，所以请注意
neutral moly take a neither radical nor the cation with it 那些孤对之一的电离事件
the cation with it 电子的丢失给了它
the cation with it therefore both are left behind in the 正电荷，现在是自由基
therefore both are left behind in the 阳离子，我将MZ标记为1/16
therefore both are left behind in the other fragment and so it says that here 对，这只是
other fragment and so it says that here 喝酒就可以了
other fragment and so it says that here so you get the radical cation why ROH is 现在它如何失去水分吧
so you get the radical cation why ROH is 消除类似于我们
so you get the radical cation why ROH is in parentheses here is because this is 谈到酒精的化学
in parentheses here is because this is 上学期对，所以氧气
in parentheses here is because this is very common for alcohols alcohols 现在，部首可以抽象
very common for alcohols alcohols 隔壁的氢气
very common for alcohols alcohols readily lose water has their neutral 对
readily lose water has their neutral 所以接你，让它能够
readily lose water has their neutral molecule and then the new radical cation 现在比法律成为水
molecule and then the new radical cation 意识到它是根本的化学反应
molecule and then the new radical cation will often fragment further to give 所以氧气的高度只是想念
will often fragment further to give 一个接一个这样的摘要
will often fragment further to give other Peaks and again remember there's a 像服务员一样，只想看看
other Peaks and again remember there's a 其他电子掉回聚会
other Peaks and again remember there's a lot going on in a mass spectrum you only 到这个好，然后想要
lot going on in a mass spectrum you only 对于水，你剩下一个
lot going on in a mass spectrum you only need to interpret that which is 自由基阳离子新分子量
need to interpret that which is 是九十八，所以你知道一个16-18
need to interpret that which is necessary to solve the problem just like 你会得到九十八水
necessary to solve the problem just like 中性分子看不到的
necessary to solve the problem just like with IR okay so here's that other 工具，但是这是根本
with IR okay so here's that other 阳离子
with IR okay so here's that other fragmentation pathway where an alcohol